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# Chemical Engineering semester 4 syllabus 2018

Chemical Engineering semester 4 syllabus 2018 – The syllabus for fourth semester in B.E Mumbai university degree course for chemical engineering has a engineering chemistry 2 which is a follow up of applied sciences chemistry from the first year.Also engineering mathematics 4 is a common subject for all branches.Other important subjects of this semester are engineering chemicals and thermodynamics, Material science engineering .

## Chemical Engineering semester 4 syllabus 2018

UNIVERSITY OF MUMBAI
Bachelor of Engineering
Chemical Engineering (Second Year – Sem.III& IV), Revised

University of Mumbai
Scheme for SE: Semester-IV

CHC 401 Applied Mathematics-IV

01 Fourier Series
? Expansion of functions in any interval (a, b) . Half range expansion;
Complex form; Parseval’s identity theorem; Orthogonal and
Orthonormal functions. NO PROOFS REQUIRED.

02 ? Fourier Integrals and Fourier Transform; sine & cosine Integrals, sine &
cosine transforms, complex transforms. NO PROOFS REQUIRED.

03 Partial Differential Equations
? Elliptic, Parabolic & Hyperbolic Equations; Laplace’s equation; One
dimensional Heat & Wave Equation, Two Dimensional wave equation.
(ONLY NUMERICAL PROBLEMS. NO PROOFS REQUIRED).
10
04 Vector Integration
? Green’s Theorem in the plain; Conservative &Solenoidal Fields. Gauss
Divergence Theorem, Stokes’ Theorem. (ONLY NUMERICAL
PROBLEMS. NO PROOFS REQUIRED).
10
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References:
? Advanced Engineering Mathematics by Erwin Kreyszig, 9TH Edition, Wiley India.
? Schuam’s outline series in Fourier series.
? Schuam’s outline series in partial differential equations.
? Partial differential equations Vol 1 by Rutherford Aris.
University of Mumbai Chemical Engineering Rev 2012-2013 Page 29
Course Code Course/Subject Name Credits

CHC402 Engineering Chemistry – II

Prerequisites:
? Basic Concepts of Physical Chemistry and Titration Analysis.
Course Objectives:
? To understand applications of EMF measurement.
? To understand the principles of different instrumental and chromatographic
techniques.
? To state and understand Nernst distribution law in extraction.
? To be able to solve numerical on solvent extraction and ion exchange.
? To understand colloidal phenomenon and its applications.
? To be able to predict the significance of active methylene group.
? To state and understand the Huckel’s rule of aromaticity and its application to
aromatic hydrocarbons and heterocyclic compounds.
? To understand the effect of various parameters on catalytic reactions.

Course Outcomes:
? Students will understand the concepts of electrochemistry, chromatographic methods,
different analytical techniques and the application of surfactants.
? Students will be aware of the significance of active methylene group during organic
synthesis and the importance of catalyst. Moreover, on the basis of Huckel’s rule,
students will be able to differentiate between aromatic and non-aromatic compounds.
? Students will be able to carry out solvent extractions, optical methods and handle
different instruments in the laboratory.
Module Contents No. of
Hours
01 Electrochemistry
? Conductance, specific conductance, equivalent conductance,
molar conductance. Effect of dilution and temperature on
conductance. Transport number.DebyeHuckel theory of strong
electrolytes. Concentration cells with and without transference
w.r.t. cations. Standard cells. Use of EMF measurement and other
technique for determination of solubility product, hydrogen ion
concentration.
8
02 Instrumental methods of Analysis
? Conductometry
Principle and types of titrations – Acid-base, precipitation and
complexometric.
? Potentiometry: Principle and types of titrations – Acid-base,
precipitation and complexometric.
? AmperometryPolarography: Methods and applications.
? Chromatography
Adsorption and partition. Study of Paper Chromatography, Thin
10
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Layer Chromatography, High Performance Liquid Chromatography,
Gas (Liquid and solid) Chromatography –Principle and their
applications.
? Optical Methods
(Principle, Instrumentation and applications) UV, IR, NMR, GC-MS
spectroscopy, flame photometry.
03 ? Ion exchange and solvent extraction techniques
Ion exchange resins, cation and anion exchangers. Desalination by ion
exchange and separation of lanthanides.
Solvent extraction. Nernst distribution law. Distribution ratio. Batch,
continuous and counter current extraction. Numericals based on
solvent extraction.
9
04 ? Colloids and surfactants
? Origin of charge on colloidal particles. Concept of electrical
double layer.
? Helmholtzand system models. Electro-kinetic PhenomenonElectrophoresis,
electro-osmosis, streaming potential and Dorn
effect (Sedimentation potential).
? Colloidal electrolytes, Donnam Membrane equilibrium Colloidal
electrolytes.
? Emulsions O/Wand W/O types, emulsifying agents, surfactants.
? Applications of surfactants in detergents, pesticide formulations
and food industry.
9
05 ? Industrially important esters and Aromaticity
? Synthesis and properties of malonic ester and aceto acetic ester
? Aromaticity and aromatic character, Huckel’s rule of aromaticity,
Aromatic character of Benzene, Naphthalene,
Anthracene,Pyrrole, Furan, Thiophene, Pyridine.
7
06 ? Catalysis
? Definition. Criteria of catalysis. Types (Homogeneous and
Heterogeneous).
? Catalytic promoters, poisons. Negative catalysis and inhibition.
Autocatalysis and Induced catalysis. Activation energy and
catalysis. Intermediate compound formation theory. Adsorption
theory. Acid-Base catalysis and mechanism. Enzyme catalysis.
Characteristics and mechanism of enzyme catalysis.
9
References:
? Organic Chemistry – I L Finar volume I and II
? Instrumental methods of Analysis – Willard, Merritt, CBS publishers and Distributors
? Instrumental Methods of Chemical Analysis -S.M.Khopkar
? A textbook of Physical Chemistry – Glasston Samuel, Macmillan India Ltd. (1991)
? Physical chemistry – Castellan G.W.Addison Hesly-Haroda Student Edition(1994)
? Inorganic chemistry – Huheey

CHC403 Chemical Engineering Thermodynamics-I

01 ? Concept of System, Surrounding, Processes, Cycle, State and
? Path function, heat and work interactions, reversible and irreversible
processes
? Concept of Internal Energy and Enthalpy
? First Law of Thermodynamics
? Application of First Law of Thermodynamics to various types of
processes, reactive processes and cycles
? Thermodynamic Analysis of Flow Processes
7
02 ? Second Law of Thermodynamics
? Concepts of heat engine, heat pump and refrigerator.
? Carnot Cycle and Carnot Principle
? Clausius Inequality
? Concept of Entropy and estimation of entropy of reversible
and irreversible processes and cycles.
? Concept of Exergy and Exergy of Chemical Processes
8
03 ? Ideal Gas and real gas behavior
? Equation of States- Van der Waals, Berthelot, RedlichKwong,
Soave Redlich Kwong, Virial and Peng Robinson.
? Applications of above mentioned equations of states to pure
fluids as well as to mixtures of gases
8
04 ? Helmholtz Energy and Gibbs Energy.
? Maxwell relations and various thermodynamic relations
? Joule Thompson effects and estimation of Joule Thompson coefficient
for gases.
8
05 ? Residual Properties- Residual Enthalpy and Entropy
? Thermodynamic Charts, Diagrams and their applications
? Fugacity and fugacity coefficient
8
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References:
? Stanley I Sandler, “Chemical and Engineering Thermodynamics”, John Wiley and
Sons.
? Richard M Feldar, Ronald W Rousseau, “Elementary Principles of Chemical
Processes”, Third Edition, Wiley publishers.
? Yunus A Cengel, Michael A Boles, “Thermodynamics- An Engineering Approach”,
McGraw Hill.
? K.V Narayanan, “A textbook of Chemical Engineering Thermodynamics”, PHI
learning.
? Rao Y.V.C, “Chemical Engineering Thermodynamics”, University Press.

CHC404 Material Science & Engineering

? Introduction of Standard Model of an atom; Young’s Double Slit
Experiment for dual nature, Wave nature of electron,
Heisenberg’s Uncertainity Principle, De Broglie’s Wavelength,
Schrodinger’s Wave Equation for 1-D Time Dependent.
7
02 ? Introduction to Magnetic Materials, Influence of Temperature
on Magnetic Behavior, Magnetic Storage, Superconductivity
? Energy Band Structures in Solids, Electrical Conduction in
Ionic Ceramics & in Polymers
? Light Interaction with solids, Atomic & Electronic
Interactions, Optical Properties of Metals, Optical Properties
of Non Metals , Opacity & Translucency in Insulators like
Glass
9
03 ? Iron-Carbon System, Phase diagram for Iron-Carbon System,
Cooling curve of Fe, Solid Phase Fe-Fe carbide phase
diagram, Development of Microstructures in Iron-Carbon
alloys
? Deformation of Materials & Strengthening Mechanisms
? Elastic Deformation, Plastic Deformation, Mechanisms of
strengthening in Metals, Recovery, Recrystallization & Grain
growth
? Crystal Imperfections
? Theories of Failure – Fatigue (cyclic stresses, S-N Curve,
Crack Theory), Fracture (Types, Principles & Mechanisms) &
10
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Creep (Types)
04 ? Polymer alloys( Difference in properties with their parent
polymers) & their applications (ABS- PS, PC-PET, SANEPDM,
PET-PS), Plastics for Packaging for food, beverages,
oil & Detergents
? Composites (FRP in detail)
? Graphite, Ceramics, Refractories, Clay
03
05 ? Mechanism & Factors influencing Corrosion
? Corrosion of Ceramic Materials
03
06 ? Factors determining choice of Materials
? MOC for Process Equipments
? MOC for handling chemicals (in reactor, storage vessel and
transportation) like Ammonium Chloride, Sulfuric Acid,
Chlorine (Dry & Wet)
07
References:
? W. D. Callister, Fundamentls of Materials Science and Engineering, Wiley
? S.D.Dawande, Process Equipment Design, Denett& Co
? Beiser-Mahajan-Choudhary, Concepts of Modern Physics, McGrawHill
? Michael Ashby-Hugh Shercliff-David Cebon, Materials- Engineering, Science,
Processing and Design, BH
? M.G.Fontana, Corrosion Engineering, Tata Mcgraw Hill
University of Mumbai Chemical Engineering Rev 2012-2013 Page 35
Course Code Course/Subject Name Credits

CHC405 Mechanical Equipment Design (MED)

1 Introduction to Chemical process Equipment Design:
Introduction to Chemical process Equipment Design Nature of process
equipment, General design procedure. Basic consideration in process equipment
design, Standards, codes & their significance, equipment classification & selection,
Fundamentals of various stress due to compression, tension, bending, torsion&
thermal stresses, Principal stress and theories of failure. Concept of hook’s law,
material behaviour and poison’s ratio, material of construction for chemical process
equipment, Design pressure, Design temperature, design stress & design loads,
Significance of factor of safety and economic considerations
4
2 Design of Unfired Pressure Vessels:
Type of pressure vessels, code & standard for pressure vessels (IS:
2825:1969), Material of Construction, Selection of corrosion Allowance & weld
joint efficiency. Thin cylinder theory for internal pressure
PART A: Pressure Vessel Subjected to Internal Pressure.
Complete design of cylindrical pressure vessel as per IS: 2825: 1969
Study, selection & design of various heads such as Flat, hemispherical,
tori-spherical, elliptical & conical.
10
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References:
? Machine Drawing by N.D.Bhatt and V.M.Panchal, Charotar publication
? Process Equipment Design by M.V.Joshi and V.V.Mahajani, Macmilan India
? Process Equipment Design and Drawing by Kiran Ghadyalji,Nandu publication.
? Process Equipment Design- Vessel design by L.E.Brownell and E.H.Young,John
Wiley
? Chemical Engineering Volume 6-Design by J.M.Coulson, J.F.Richardson and
R.H.Sinnott,Pergamon Press.
? Pressure Vessel Handbook by Eugene F.Megyesy,Pressure vessel company
Openings/nozzles & manholes etc.
Flanged joints:
Bolt design & selection
Flange dimensions & optimization for bolt spacing
PART B: Pressure Vessel Subjected to External Pressure.
Design of shell, heads nozzles, flanged joints & stiffening rings as per IS
2825: 1969
Appendix F by use of charts.
Analytical approach by elastic bucking & plastic deformation.
3 Storage Vessels:
Study of Various types of storage vessels and application.
Atmospheric vessels, vessels for storing volatile & non-volatile liquids.
Storage of gases, Losses in storage vessel. Various types of roofs used for storage
vessels, Manholes, Nozzles and mounting. Design of cylindrical storage vessels as
per IS: 803 should include base plates, shell plates ,roof plate and wind girders
6
4 Agitators:
Study of various types of agitators & their application, Baffling, Power
requirement of agitators & their applications, system which includes design of shaft
based on equivalent twisting moment, equivalent bending moment and critical
speed. Design of blades & Blade assembly, key & key ways. Design of rigid flange
coupling, Study of seals and design of stuffing box and gland
6
5 Reaction Vessels:
Introduction, Classification of reaction vessels, Material of Construction,
Heating system, Design of vessel, Study & design of various types of jackets like
plain and half coil.
4
6 Vessel Supports:
Introduction & classification of support. Design of skirt Support
vibration. Design of base plates, skirt bearing plate, anchor bolt and bolting chair.
Introduction to bracket support.
5
7 Equipment fabrication and inspection:
Metal forming techniques (bending, Rolling, Forming) & Metal Joining
techniques – welding (Gas of Arc & Electric) for various types such as Butt, Lap,
fillet, corner.
4
University of Mumbai Chemical Engineering Rev 2012-2013 Page 37
Course Code Course/Subject Name Credits

CHC406 Solid Fluid Mechanical Operations

Prerequisites
? Fluid Flow Operations
? Engineering Mechanics
? Differential Equations
Course Objectives
? Understanding basic principles of particle size measurement and distribution.
? Basic knowledge in particle technology (particle size, shape, specific surface).
? Ability to understand phenomena related to specific surface of particles.
? Understanding concepts of sedimentation, flow through packed bed, filtration.
? Ability to understand solid mixing and solid conveying.
Course Outcomes
? The student would understand the concept of particle size measurement and
distribution.
? The student would understand the concept of hindered settling, sedimentation and
particle mechanics.
? The student would understand the concept of solid mixing, solid storage and solid
conveying.
? The student would understand the concept of filtration.
Module Contents No. of
hours
01 ? Introduction:-Scope & Application of Solid Fluid Operation.
? Particle Size Analysis:-Particle Size Measurement & distribution.
? Sieve Analysis Screening Equipments, Capacity & Effectiveness.
5
02 ? Introduction to Size Reduction Equipments,
? Their Selection & Power Requirement in Milling Operations.
5
03 ? Storage & Conveying of Solids: – Introduction to Storage Solids, Bins,
Hoppers & Silos.
? Jensen’s Equation.
? Conveying of Solids: – Introduction to Conveying of Solids, Belt
Conveyor, Bucket Conveyor, Pneumatic Conveyor &Elevators.
7
04 ? Flow through Packed Beds:-Characteristics of Packing, Ergen’s Equation,
Flow of a single fluid through a packed bed, Problems of Channeling &
Wetting.
? Fluidization.: – Fluidization Characteristics, aggregative & particulate
fluidization, Minimum Fluidization, Voidage& Minimum Fluidization
Velocity, Voidage Correlation, Gas-Solid fluidization characteristics
? Filtration:-Flow through Filter Cakes & Medium
9
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? Washing (Numerical), Const Rate & Pressure Filtration, Filter aids,
Selection of filtration Equipment.
05 ? Particle Mechanics:-Motion of Particles in fluids, Effect of particle shape,
Stokes Law, Hindered Settling.
? Sedimentation: – Gravity Settling, Batch Sedimentation, Kynch Theory of
Sedimentation.
? Area & Depth of Thickener.
? Particle Separation Based on motion of Particles through fluids:-Froth
floatation & Elutriation.
9
06 ? Mixing of Solids & Paste.
? Gas-Solid Separation Equipment:-Fabric Filter, Cyclone Separator,
Electrostatic precipitator
4
References:
? Unit Operations of Chemical Engineering, W C McCabe & J C Smith, McGraw Hill.
? Chemical Engineering, Vol. II, J M Coulson and J F Richardson, Pergamon press.
? Perry’s Handbook for Chemical Engineers, Robert H. Perry & Don W. Green,8th
edition, McGraw Hill.
? Unit Operations by Foust
University of Mumbai Chemical Engineering Rev 2012-2013 Page 39
Course Code Course/Subject Name Credits

CHL407 Engineering Chemistry Lab-II

List of Experiments Suggested:
? Organic spotting: Identification of organic compounds at least 05.
? Potentiometric titrations.
? Titration of strong acid and strong base potentiometrically.
? Determination of solubility and solubility product of AgCl.
? pH-metry.
? Determination of dissociation constant of dibasic organic acids such as malonic acid,
succinic acid.
? Conductometric Titrations.
? Titration of strong acid with strong base.
? Weak acid against strong base.
? Titration of mixture of weak acid and strong acid against strong base.
? Flame photometry.
? Determination of Na / K / Ca present in the given sample.
? Chromatography.
? Estimation of Sodium by Ion Exchange chromatography.
? Paper Chromatography and TLC [Demonstration of techniques].
? Spectro-photometry.
? Estimation of Fe3+
ions by Spectrophotometry.
? Organic Estimations.
? Estimation of Glucose Iodometrically.
? Estimation of Ester by Hydrolytis.
? Volume strength and amount of H2O2.

CHL408 Chemical Engineering Lab (SFMO)

List of Experiments Suggested:
? Sieve Analysis
? Effectiveness of Screen
? Size Reduction by Jaw Crusher
? Size Reduction by Hammer Mill
? Size Reduction by Ball Mill
? Batch Sedimentation
? Flow through Packed Bed
? Flow through Fluidized Bed
? Filtration
? Sigma Mixer

CHL409 MED Lab 1

List of Suggested Drawing Sheets
? Assembly and Detailed drawings of Machine elements like shafts, key
and keyways, Fasteners, Types of welding technique and symbols.
? Assembly and Detailed drawings of Pressure vessel parts such as types of
heads, Nozzle joints and flanged joints, mountings (Sight glass, Light
glass, man hole etc)
? Assembly and Detailed fabrication drawings of complete pressure vessel
and its parts to a recommended scale.
? Assembly and Detailed fabrication drawings of complete storage vessel
and its parts to a recommended scale.
? Assembly and Detailed fabrication drawings of Agitator vessel and its
parts like coupling and stuffing box to a recommended scale
? Assembly and Detailed fabrication drawings various types of reaction
vessel to a recommended scale
? Assembly and Detailed fabrication drawings of various types supports to
a recommended scale